EDX-7200 - Opties

Energy Dispersive X-ray Fluorescence Spectrometer

Screening Analysis Kits (Option)

Ideal for RoHS, ELV, and Halogen Screening

The optional screening analysis kits allow even beginners to start RoHS, halogen, or antimony screening analysis right from the day of purchase.
Simply mount the sample, select the analysis conditions, enter the sample name, and wait for the results. The analysis results are displayed with a pass/fail evaluation after just a few minutes. RoHS extended elements (P, Cl, Sn, Sb) are also supported by the optional RoHS enhanced screening kits, and ease of use has been improved with a more accurate threshold evaluation.

Ideal for RoHS, ELV, and Halogen Screening

Analytical results window using the RoHS, Halogen and Antimony screening kit

Internal Calibration Curves and Automatic Calibration Curve Selection

Internal Calibration Curves and Automatic Calibration Curve Selection

Standard value (ppm)

Internal calibration curves
Internal calibration curves are provided for many materials, making it unnecessary to provide a large number of standard samples.

Automatic calibration curve selection
The software automatically selects the best calibration curve for the material, freeing the user from the need to select analysis conditions.
As an incorrect calibration curve selection can result in a large error in the quantitation results, this function contributes to more reliable data.

Shape correction
The fluorescent X-ray and scattered X-ray intensities are compared for each element (BG internal standard method) to eliminate the effects of the sample shape and thickness in the quantitation values.

Automatic Measurement Time Reduction

  • This function automatically switches to the next analysis channel if a controlled substance clearly has a high or low concentration, making evaluation possible while measurement is underway. This achieves more efficient screening analysis.

    Automatic Measurement Time Reduction

    By improving the count rate, the screening accuracy has been improved with the same measurement time as conventional equipment.
    In addition, the software reduces the time that was unconditionally measured until the time set in the gray zone.

  • Automatic Measurement Time Reduction
Time-saving function diagram

Time-saving function diagram

Screening Simple Setup Screen

  • Threshold Values
    A threshold value can be set for each material and element. The screening evaluation method changes according to how the threshold values are set.

    Evaluation Charac ter String
    Character strings can be set for display in the analysis results when the threshold value is not exceeded, in the gray zone, and when the threshold value is exceeded.

    Report Template
    Set the report style from among the templates supplied as standard.

  • Simple Setup Screen of RoHS Screening Analysis Kit

    Simple Setup Screen of RoHS Screening Analysis Kit

Three screening analysis kits are available to suit dif ferent applications.

  •  

    RoHS Screening Analysis Kit

    RoHS Screening Analysis Kit
    Kit for screening cadmium, lead, mercury, chromium, and bromine. Polyethylene samples containing these five elements are supplied in the kit for instrument management.

  •  NEW 

    Phosphorus (P) Screening Analysis Kit

    Phosphorus (P) Screening Analysis Kit
    Kit for screening of phosphorus in flame retardants in resins. Can also be used for trace evaluation. Samples containing phosphorus are supplied in the kit for instrument management.
    *See page 18 of this brochure for an example of phosphorus (P) screening analysis.

 

 

  •  

    RoHS and Halogen Screening Analysis Kit

    RoHS and Halogen Screening Analysis Kit
    In addition to cadmium, lead, mercury, chromium, and bromine, this kit supports the screening of chlorine in plastics. Polyethylene samples containing these six elements are supplied in the kit for instrument management.

  •  NEW 

    Tin (Sn) Screening Analysis Kit

    Tin (Sn) Screening Analysis Kit
    Kit for screening of Tin (Sn) in resins. Can also be used for trace evaluation. Samples containing tin are supplied in the kit for instrument management.
    *The P and Sn screening kits cannot be used alone. Be sure to use them with one of the RoHS screening analysis kits (described on the left).

     

  • RoHS, Halogen, and Antimony Screening Analysis Kit

    RoHS, Halogen, and Antimony Screening Analysis Kit
    In addition to cadmium, lead, mercury, chromium, and bromine, this kit supports the screening of chlorine and antimony in plastics.
    Polyethylene samples containing these seven elements are supplied in the kit for instrument management.

  •  

EDXIR-Analysis™ Software (Option)

EDXIR-Analysis Software

EDXIR-Analysis software is specially designed to perform qualitative analysis using data acquired by an energy dispersive X-ray (EDX) fluorescence spectrometer and a Fourier transform infrared (FTIR) spectrophotometer.
This software is used to perform an integrated analysis of data from FTIR, which is excellent at the identification and qualification of organic compounds, and from EDX, which is excellent at the elementary analysis of metals, inorganic compounds and other content. It then pursues identification results and the degree of matching. It can also be used to perform EDX or FTIR data analysis on its own.
The library used for data analysis (containing 485 data as standard) is original to Shimadzu, and was created through cooperation with water supply agencies and food manufacturers. Additional data can be registered to the library, as can image files and document files in PDF format. It is also effective for the linked storage of various types of data as electronic files.

Integrated Analysis of Contaminant Data and Data Comparisons for Conrmation Tests

To perform qualitative analysis automatically, simply click “Analyze Both Data” and select the EDX/FTIR data*1. This heightens the efficiency of data analysis and provides strong support for contaminant analysis.
In addition to a list of hits, the integrated data analysis results show EDX profiles and FTIR spectra found as hits from the library. If the user wishes to browse the respective data analysis results, they can be checked by clicking "Single".
In addition, with the data comparison function, which calculates the degree of matching between the actual measured data and the data registered in the library, the software can be used for countermeasures against "silent change"*2 and for other confirmation tests.
Clicking the “Print” button prints the results in a fixed format and also saves them in Word format*3.

  • Using the EDX profile, data are classified as inorganic, organic, and mixture. Integrated data analysis is performed by applying priority levels to each classification. (Patent pending)
  • A term used in Japan to indicate changes to materials by suppliers without the knowledge of the manufacturers.
  • Microsoft® Word must first be installed.

The examples here show an integrated analysis of black rubber contaminant data acquired and a data comparison for a polyvinyl chloride (PVC) examination object and the standard product. From the integrated data analysis results, it is evident that the black rubber contaminant is acrylonitrile-butadiene rubber (NBR), which contains calcium carbonate and zinc stearate. In addition, from the data comparison, the degree of matching between the PVC examination object and the standard product is 0.8506. Lead (Pb) and acrylic were detected from the EDX and FTIR data, but were not detected in the standard product. Accordingly, it is surmised that the examination object contains components different to those in the standard product.

Integrated Analysis of Contaminant Data and Data Comparisons for Conrmation Tests

Data Browsing and the Registration, Editing, Deletion of Data, Images, Document Files

By clicking "Edit" and selecting an existing library, the data, images and documents registered in the selected library can be browsed. Data can be registered, edited, deleted. A new library can also be created.
In addition, if data for a sample were acquired by instruments other than EDX and FTIR instruments (such as a chromatograph, mass spectrometer, or surface observation system), it can be converted into PDF format and then registered, enabling linked storage to the EDX/FTIR data.

Data Browsing and the Registration, Editing, Deletion of Data, Images, Document Files

Sample Holder/Stocker for Contaminant Measurement EDXIR-Holder™ (Option)

Measure the Samples Kept in the Holder with EDX and FTIR
The Holder Can Be Used as the Sample Stocker after the Measurement

Enables More Efficient Analyses

This foldable holder consists of an adhesive layer with samples attached and polypropylene film designed for a fluorescence X-ray. When using EDX for measurement, close the holder and place the polypropylene film directly to the irradiation side (downside). When using FTIR for measurement, open the holder and press the samples attached to the adhesive layer against the ATR prism. This enables the replacement of samples, at a minimum, saving on labor and making analysis more efficient.

Prevents Loss of Samples

Close the holder after the measurement and it can be used as a sample stocker. It is not necessary to transfer the samples to other containers, so there is no danger of losing samples.

Prevents Loss of Samples

Small Spot Analysis Kit (Option)

  • For Analysis of Small Contaminants and Defect Analysis in Small Regions

    This option can be used to analyze even smaller areas by replacing the collimator plate and sample observation camera. It is especially useful for analyzing trace foreign matter and defects in micro areas, and measuring plating thickness.

    Minimum 0.3 mm X-Ray Irradiation Diameter
    The excitation X-rays can be collimated to 0.3 mm in diameter, which is effective for the high-accuracy analysis of small contaminants and for defect analysis in small regions, analyses difficult with standard specifications (minimum 1 mm in diameter).

    Enlarged Sample Images without Image Quality Degradation
    This system supports smaller samples, which heightens the visibility of sample observation images. Users can switch to an enlarged image approximately 2.5 times larger than a previous image, without image quality degradation.

    Automatic Four-Stage Switching Between 0.3, 1, 3, and 10 mm in Diameter
    The irradiation diameter automatically switches between 0.3, 1, 3, and 10 mm in diameter.
    This system supports not only the analysis of small spots but also macro composition analysis at 10 mm in diameter.
    Note: The irradiation diameter is the size on the sample surface.

    Automatic Four-Stage Switching Between 0.3, 1, 3, and 10 mm in Diameter
  • For Analysis of Small Contaminants and Defect Analysis in Small Regions

Analysis ExampleーSmall Metal Powder (Approx. 0.1 mm in Diameter) Adhered to the Surface of Snacks

A small metal powder approximately 0.1 mm in diameter adhered to the commercially available snacks was analyzed with irradiation diameters of 1 mm and 0.3 mm, respectively. At an irradiation diameter of 1 mm, the overall background is significantly increased due to the influence of scattered X-rays from the surrounding area of the metal powder (snacks), resulting in a poor S/N ratio. At an irradiation diameter of 0.3 mm, however, the influence of scattered X-rays from the surrounding area is small, and peak profiles with a good S/N ratio are obtained.
Copper (Cu) and Zinc (Zn) are detected as the major components with both irradiation diameters. It indicates that the metal powder is brass regardless of the irradiation diameter used. However, at 0.3 mm in diameter, the peak of Lead (Pb) is also identified, which suggests that the metal powder is “free cutting brass”.
By using an irradiation diameter of 0.3 mm, more accurate analyses can be performed, even for small contaminants on substances such as organic materials that strongly scatter X-rays.

Analysis Example—Small Metal Powder (Approx. 0.1 mm in Diameter) Adhered to the Surface of Snacks

Options

  • Vacuum Measurement Unit
    P/N 212-25425-42
    Use this unit for sensitive measurements of light elements. It requires space for installation of a rotary pump and switch box at the side or rear of the desk supporting the main unit.
  • Helium Replacement Measurement Unit
    P/N 212-25440-42
    This unit is used for highly sensitive measurements of light elements in liquid samples. Does not include a helium cylinder or regulator.

 

  • Turret Unit

    Turret Unit
    P/N 212-25389-41
    Turret for 12 samples. It permits continuous measurements of samples up to 32 mm in diameter. It improves throughput, especially for measurements in a vacuum or helium atmosphere.

  •  

    Screening Analysis Kits
    P/N 212-11110-41
    RoHS/ELV Screening Analysis Kit
     With check samples for five elements

    P/N 212-11111-41
    RoHS and Halogen Screening Analysis Kit
     With check samples for six elements

    P/N 212-11112-41
    RoHS, Halogen, and Antimony Screening Analysis Kit
     With check samples for seven elements

    P/N 212-11112-41
    RoHS, Halogen, and Antimony Screening Analysis Kit
     With check samples for seven elements

    P/N 212-11062-41
    Phosphorus (P) Screening Analysis Kit

    P/N 212-11061-41
    Tin (Sn) Screening Analysis Kit

Sample Cells

  • 3571 General Open-End X-Cell (no lid)

    3571 General Open-End X-Cell (no lid)
    P/N 219-85000-55 (100 cells/set)
    (Outer diameter: 31.6 mm, volume: 10 mL)
    Polyethylene sample cell for liquid and powder samples.

  • 3529 General X-Cell (with lid)

    3529 General X-Cell (with lid)
    P/N 219-85000-52 (100 cells/set)
    (Outer diameter: 32 mm, volume: 8 mL)
    For liquid samples. Equipped with a relief hole and liquid retainer in case of liquid expansion.

 

  • 3577 Micro X-Cell

    3577 Micro X-Cell
    P/N 219-85000-54 (100 cells/set)
    (Outer diameter: 31.6 mm, volume: 0.5 mL)
    For trace samples. Recommended for use with a collimator.

  • 3561 Universal X-Cell

    3561 Universal X-Cell
    P/N 219-85000-53 (100 cells/set)
    (Outer diameter: 31.6 mm, volume: 8 mL)
    For liquid and thin-film samples. Equipped with a relief hole and liquid retainer in case of liquid expansion. Equipped with a ring to tightly hold thin-film samples with film.

 

 

  • Polyester Film
    P/N 202-86501-56 (500 sheets/set)
    Sample-holding film (for heavy element analysis)
  • Polypropylene Film
    P/N 219-82019-05 (73 mm W × 92 m roll)
    Sample-holding film (for light element analysis)